Efficient Ce3+–Tb3+ Energy Transfer in BASL-Ce/Tb Co-Doped Glass for Photonic Applications

Case ID:
UA26-058
Invention:

This invention describes a method of fabricating novel low-SWaP (size, weight, and power) lasers and magneto-optical devices based on innovative Ce3+/Tb3+ co-doped BASL glass. The ability of this glass to efficiently support energy transfer at wavelengths up to 390 nm, beyond conventional limits, makes it highly promising for use in radiation-hardened visible microchip lasers, non-planar ring oscillators, fiber lasers, and magnetic field sensors.

Background: 
Silicate glasses are popular for their strength, durability, and thermal stability, making them easier to process than other glass types. However, they struggle to hold high levels of Ce³⁺ because it often oxidizes to Ce⁴⁺ during melting, reducing luminescence. Alternatives like heavy metal oxide or fluoride glasses offer better optical properties but are hard to produce in large volumes and maintain Ce³⁺ efficiency. Ce³⁺-doped materials are valuable for photonics due to their broad UV-visible luminescence and radiation resistance, but crystals and films are costly and brittle. Newly developed Ce³⁺-doped boron-aluminosilicate (BASL) glass solves these issues by combining durability with stable Ce³⁺ doping, enabling efficient Ce to Tb energy transfer for advanced photonic applications.

Applications: 

  • Visible microchip lasers
  • Non-planar ring oscillators
  • Fiber lasers
  • Magnetic field sensors
  • Photonics manufacturing
  • Magneto-optic devices


Advantages: 

  • Efficient energy transfer
  • Broad excitation range
  • Thermal and chemical stability
Patent Information:
Contact For More Information:
Richard Weite
Senior Licensing Manager, College of Optical Sciences
The University of Arizona
RichardW@tla.arizona.edu
Lead Inventor(s):
Viktor Dubrovin
Keywords: